Abstract

Two stable supramolecular microporous polymers with double-layer structures, [Co(AIP)(BPY) 0.5 · H 2O] n · 2nH 2O ( 1) and [Ni(AIP)(BPY) 0.5 · H 2O] n · 2nH 2O ( 2), were constructed from AIP (5-aminoisophthalate) and BPY (4,4′-bipyridine) under hydrothermal conditions. Both of them exhibit rarely reported (3,4)-connected (6 3)(6 58) topology and interesting water-induced reversible transformation properties that are confirmed by PXRD studies.

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