Abstract
Two coordination polymers (CPs){[M(L)2(H2O)2]·2H2O}n (M=Co (1) and Mn (2), HL=4-(3H-imidazo[4,5-b]pyridin-2-yl) benzoic acid) have been prepared under hydrothermal method and systematically characterized. The catalytic properties of the two CPs were investigated, the results showed that CP 1 could be used to catalyze CO2 cycloaddition reactions efficiently under eco-friendly, solvent-free conditions. The influencing factors and catalytic mechanism of cycloaddition reaction were discussed. Moreover, CP 2 exhibited catalytic performance for cyanosilylation reaction. The recycling experiments showed that the CPs 1 and 2 could be recovered and reused at least 5 reaction cycles without an obvious decrease of catalytic activity.
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