Tuning structural, electrical, dielectric and magnetic properties of Mg–Cu–Co ferrites via dysprosium (Dy3+) doping

Abstract

In current research work, Dy3+ substituted Mg0.5Cu0.25Co0.25Fe2‒xDyxO4 (0.0 ≤ x ≤ 0.04 with the step interval of 0.01) soft ferrites were synthesized by the sol–gel auto combustion method. The prepared samples were characterized by the techniques using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), Fourier transform infrared (FTIR) spectroscopy, current–voltage (I–V) measurement, LCR meter, vibrating sample magnetometer (VSM) and Raman. XRD data reveal that the average crystallite size is 49.71 nm and the lattice constant is 0.83703 nm for sample x = 0.03. The non-uniform grain growth was demonstrated by micrographs and impurity-free elemental composition was observed from EDX analysis. The DC resistivity has an increasing and decreasing trend in ferromagnetic and paramagnetic regions with an increase in temperature. Moreover, the high resistivity is observed with the order of 1010 Ω·cm, and the activation energy is 0.944 eV for samples x = 0.03. The dielectric parameters including dielectric constant, dielectric losses, and impedance gradually decrease with the increase in frequency from 8 Hz to 8 MHz. The minimum dielectric loss at high frequency is found for sample x = 0.03. The coercivity (Hc) and saturation magnetization (Ms) are found in the ranges of 520.82–544.02 Oe and 20.5841–21.1473 emu/g, respectively. These observations confirm that dysprosium (x = 0.03) doped MCC-soft ferrites may be applicable in transformer cores, microwave absorbance, and telecommunication devices.