Abstract
Benefiting from improved stability due to interlayer van der Waals interactions, few-layer fullerene networks are experimentally more accessible compared to monolayer polymeric C60. However, there is a lack of systematic theoretical studies on the material properties of few-layer C60 networks. Here, we compare the structural, electronic and optical properties of bilayer and monolayer fullerene networks. The band gap and band-edge positions remain mostly unchanged after stacking two layers into a bilayer, enabling the bilayer to be almost as efficient a photocatalyst as the monolayer. The effective mass ratio along different directions is varied for conduction band states due to interlayer interactions, leading to enhanced anisotropy in carrier transport. Additionally, stronger exciton absorption is found in the bilayer than that in the monolayer over the entire visible light range, rendering the bilayer a more promising candidate for photovoltaics. Moreoever, the polarisation dependence of optical absorption in the bilayer is increased in the red-yellow light range, offering unique opportunities in photonics and display technologies with tailored optical properties over specific directions. Our study provides strategies to tune electronic and optical properties of 2D polymeric C60via the introduction of stacking degrees of freedom.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call