Tunable Topological Wetting State of Water Droplets on Planar Surfaces: Closed-Loop Chemical Heterogeneity by Design.

Abstract

Understanding droplet wetting on surfaces has broad implications for surface science and engineering. Here, we report a joint theoretical/experimental study of the topological wetting states of water droplets on chemically heterogeneous closed-loop and planar surfaces. Interestingly, we provide both simulation and experimental evidence of biloop or even multiloop transition wetting states of water droplets. Specifically, in our molecular dynamics simulations, we designed surfaces patterned with alternating closed-loop superhydrophilic and hydrophobic nanobands. On these surfaces, we find that the contact shape and contact angle of water nanodroplets can be tailored by changing the shape of the nanobands. Overall, the contact angle of the droplets is dependent on the initial location of the water droplet, the interaction between the water molecules and hydrophobic particles, and the width of the superhydrophilic and hydrophobic nanobands. The wetting-state transition dynamics is also dependent on the nanoband shape. In the biloop or multiloop transition wetting states, the three-phase contact line is not limited to only one loop nanoband but can be located at two or more distinct loops. Guided by the simulation results, the corresponding experiments confirmed the presence of topological wetting states and multiloop wetting states on planar chemically heterogeneous surfaces with closed-loop microbands. Importantly, we provide an explanation of the mechanism of the topological wetting state formation and transition. Our study facilitates a deeper understanding of the droplet-surface interactions and offers an alternative way to tune the droplet shape and contact angle on planar surfaces by engineering chemically heterogeneous surface textures.