Abstract
This paper describes for the first time the 1,3-dipolar cycloaddition of aryl azides to the vinylic bond of enamides, represented by the N-vinyllactam N-vinyl-2-pyrrolidinone (NVP) (Ia) and the open-chain enamide, N-methyl-N-vinylacetamide (NVA) (Ib). Mechanistically, enamides react like enamines in azide cycloaddition reactions to yield 1-aryl-5-amido-1,2,3-triazolines (III)
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