Trends in the dissolution of metals from sediments collected during the Umitaka-Maru cruises using the microwave-acid digestion technique

Abstract

Sediment samples were collected during the research vessel Umitaka-Maru cruises in the Gulf region from 15–16 December 1993 and 15–27 December 1994, from 19 and 24 locations, respectively. These samples were subjected to trace metal analysis to determine the 1991 Gulf War oil spill environmental impact in the area. The samples investigated are texturally classified into two main sediment classes: sand and mud. The total concentrations of lead, nickel, and vanadium found in the sediments from individual stations were investigated. The differences in trace metal concentrations reflect the variation in the overall composition of their host sediments. To better appraise the trace element composition of their host sediments and to determine the factors governing the trace metal distribution, the data were sub-divided into five groups among 1993 collections and seven groups during 1994. The concentration ranges of all three metals, lead (0.2–4.85), nickel (4.90–86.00), and vanadium (2.00–38.00) varied in different stations among the groups. The partitioning of trace elements between the detrial and non-detrital fractions of the sediments shows that: 1) The high concentrations of elements in mud is coupled with the increase in the detrital fraction; 2) In muddy sand sediments, nickel is bonded to the structural lattice of detrital minerals, whereas vanadium and lead held in the environmentally mobile fraction; and, 3) In sandy mud sediments, Ni is found in the detrital fraction, whereas V to slightly less extent and Pb show their non-detrital nature. The data were compared with unpolluted sediments throughout the ROPME Sea and worldwide, so the effect of anthropogenic enrichment upon the absolute concentration of the elements is minimal.