Treatment of young and stabilized landfill leachate by integrated sequencing batch reactor (SBR) and reverse osmosis (RO) process

Abstract

In this paper, the performance and effectiveness of combined sequencing batch reactor (SBR) and reverse osmosis (RO), as well as differences in treating young and matured landfill leachate, was investigated. Samples of young and stabilized leachate were collected from a municipal landfill in north-eastern Poland. The general pollution parameters, organic and inorganic indicators were determined in raw leachate and after each step of leachate treatment. The performance characteristics of the reverse osmosis system were made based on permeate flux, electroconductivity removal rate, concentration factor and removal rate. The use of biological pre-treatment had a good efficiency (>98% for both leachate) in ammonia nitrogen removal. The SBR treatment effectiveness for BOD (64%), Fe (29%), Cl− (0.2%) and Total Organic Carbon (-5.3%) was lower for young leachate compared to a stabilized. Pretreated leachate was directed to a RO system which was characterized by better operational parameters during the filtration of stabilized leachate: the average permeate flux was higher by 3.3 L/m2⋅s⋅10−6 and the filtration time was shorter by 110 min compared to the young leachate. The main reason of membrane clogging during young leachate filtration was a higher content of organic matter and its neutralization by Ca2+ and N-NH4+ presented in leachate, causing clogging of negatively charged RO membrane. Another reason could be complex formation between iron and natural organic matter that may precipitate on the membrane surface or inside the pores. This study has shown a high removal efficiency (over 80%) of the integrated SBR-RO method for all analyzed parameters.