Transport phenomena of bubble growth coupled with chemical reaction during laser-induced photothermal reduction and deposition processes

Abstract

Laser assisted low-temperature nano/microfabrication of functional materials on a flexible or rigid substrate using water-based liquid precursor have gained significant attention owing to its high process efficiency and low environment impact. Both of which are essential for the green and low-carbon manufacturing technologies needed for the next generation of electronic devices. Laser induced photo-hydrothermal synthesis (LIPHS) utilizes thermally induced reductive reaction in a liquid precursor to synthesize and deposit nano/micro-patterns on temperature sensitive substrates. During LIPHS, microbubble generation is inevitable as a result of byproduct gas formation and liquid-vapor phase change of the precursor. Transport phenomena of the laser-induced reduction reaction coupled with microbubble dynamics on the liquid-vapor-solid triple contact interface significantly affects the quality of fabricated nano/microstructures. Herein, we investigated microbubble formation and growth on the substrate surface during a LIPHS process for silver on a polyimide substrate surface. Framewise growth of microbubble was captured for different laser powers and solute concentrations to reveal the time dependent bubble diameter variation. It was found that the bubble size and growth rate decreased with increasing solute concentration owing to increased boiling point of the precursor. Bubble temperature and reduction reaction rate were obtained by theoretical analyses on the microbubble growth rate. Transient solid-liquid-vapor triple contact point temperature of the microbubble during the LIPHS process was obtained from a numerical simulation to develop a comprehensive model the first time for predicting the chemical reaction rate. The proposed model was validated experimentally with a relative error of 6.2% at the highest reaction rate.