Transport in conductors and rectifiers: Mean-field Redfield equations and nonequilibrium Green's functions

Abstract

We derive a closed equation of motion for the one particle density matrix of a quantum system coupled to multiple baths using the Redfield master equation combined with a mean-field approximation. The steady-state solution may be found analytically with perturbation theory. Application of the method to a one-dimensional noninteracting quantum wire yields an expression for the current that reproduces the celebrated Landauer's formula. Nonlinear rectification is found for the case of a mesoscopic three-dimensional semiconductor $p\ensuremath{-}n$ junction. The results are in good agreement with numerical simulations obtained using nonequilibrium Green's functions, supporting the validity of the Redfield equations for the description of transport.