Abstract

Poly (amic acid) s (PAAs) were synthesized using 4,4′-(hexafluoroisopropyl-idene) diphthalic anhydride (6FDA) and two types of diamines—bis(3-aminophenyl) sulfone (BAS) and bis(3-amino-4-hydroxyphenyl) sulfone (BAS-OH). Two series of transparent polyimide (PI) hybrid films were synthesized by solution intercalation polymerization and thermal imidization using various concentrations (from 0 to 1 wt%) of organically modified clay Cloisite 30B in PAA solution. The thermo-mechanical properties, morphology, and optical transparency of the hybrid films were observed. The transmission electronic microscopy (TEM) results showed that some of the clays were agglomerated, but most of them showed dispersed nanoscale clay. The effects of -OH groups on the properties of the two PI hybrids synthesized using BAS and BAS-OH monomers were compared. The BAS PI hybrids were superior to the BAS-OH PI hybrids in terms of thermal stability and optical transparency, but the BAS-OH PI hybrids exhibited higher glass transition temperatures (Tg) and mechanical properties. Analysis of the thermal properties and tensile strength showed that the highest critical concentration of organoclay was 0.50 wt%.

Highlights

  • Polyimide (PI), which has been used for a long time, was mainly studied for military purposes when it was first developed [1,2]

  • PI has been applied as an integrated material for semiconductor materials such as liquid crystal display (LCD) and plasma display panel (PDP) because of its low weight and its ability to improve electronic products

  • We described the effect of -OH groups in PI hybrids and compared the properties of the two PI hybrids synthesized using BAS and BAS-OH diamine monomers

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Summary

Introduction

Polyimide (PI), which has been used for a long time, was mainly studied for military purposes when it was first developed [1,2]. PIs containing trifluoromethyl groups have been synthesized that show a high modulus, low thermal expansion coefficient, and good solubility in conventional organic solvents [9,10,11]. Another method is to use a copolyimide (Co-PI) using a specific monomer. Several methods are used to increase the physical properties of the blend, including hydrogen bonding using the hydroxyl (-OH) group between the polymer chain and the filler. We described the effect of -OH groups in PI hybrids and compared the properties of the two PI hybrids synthesized using BAS and BAS-OH diamine monomers

Materials
Preparation of PI Hybrid Films
Characterization
FT-IR and NMR Spectra
30 B observed was observed
Wide angle X-ray
Morphological Analysis by TEM
Thermal Behavior
Mechanical Tensile Properties
Optical
10. The the BAS
Conclusions
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