Transmission electron microscopy study of a high burnup U-10Zr metallic fuel

Abstract

To support the development of U-10 wt.% Zr (U-10Zr) metallic fuel for Generation IV sodium-cooled fast reactors, we analyzed a Na-bonded solid U-10Zr fuel cross-section that was irradiated to a burnup of approximately 13.2 at.% at the Fast Flux Test Facility (FFTF). Advanced characterization techniques, including site-specific sample preparation by focused ion beam (FIB) and scanning transmission electron microscopy (STEM), were used to reveal the Zr redistribution and characterize the fuel matrix and secondary phases (such as solid fission products) present at the end of life. Results showed that the fuel pin cross-section is divided into three major concentric zones: a Zr-rich central region, a Zr-lean intermediate region, and a Zr intermediate peripherical region. The phase characterization revealed that the irradiation environment enhanced the development and stabilization of phases not predicted by the standard equilibrium U-Zr phase diagrams. Comparing the current results with the ones from previous studies, it is reaffirmed that the radial temperature profile and the time spent in the reactor, rather than the fuel burnup, are the two factors that most influence the formation of redistribution zones and their extension along the fuel cross-section. Various solid fission products, such as lanthanides, ZrRu, BaTe, CsI, and Ba and Sr oxides, precipitated inside the fission gas pores. This study provides unprecedented nanoscale understandings in the irradiated U-10Zr fuel system that may benefit fuel performance modelling and advanced fuel development.