Abstract
AbstractA halogen and base‐mediated [3+3]‐cycloaddition reaction of in situ generated azaoxyallyl cations with in situ formed C,N‐cyclic azomethine imines is reported. This one‐pot transition metal‐free cycloaddition process exhibits broad substrate scope, excellent functional group tolerance, and affords a series of biologically important isoquinoline‐fused triazines in good to excellent yields, which containing valuable alkenyl C−X bonds (X=Br, I).magnified image
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