Abstract
AbstractTransition–lanthanide heterometal–organic frameworks (HMOFs) have attracted increasing interests in recent decades because of their advantageous features as potential molecular materials, such as fascinating structural topologies, and their versatile and chemically tunable properties. Since the chemical and physical properties originated from d and f electrons are totally different, it is difficult to synthesize HMOFs in contrast to homometallic MOFs and it has showed that distinguishing characteristics with regard to structures and properties are observed in HMOFs. Herein the synthetic strategy, structures, and properties of luminescence, magnetism, adsorption, etc. are reviewed in this chapter to help readers to understand various aspects of HMOFs.KeywordsAdsorptionHeterometallic MOFsLuminescenceMagnetismSynthetic strategy
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