Abstract
Thin films of a number of transition metal oxides, when employed as electrodes in the appropriate electrochemical cells, exhibit electrochromism by a reversible ion-insertion mechanism. These oxides may be divided into two groups, those which colour cathodically by a reduction process, and those which colour anodically by an oxidation process. At present the former class is known to contain the oxides of W, Mo, V, Nb and Ti, whereas those of Ir, Rh, Ni and Co are contained in the latter class. A two-part in-depth review is given of the electrochromic behaviour of thin films of these oxides. This part of the paper considers cathodically coloured oxides, with anodically coloured oxides the subject of the second part. Special attention is given to tunstic oxides as the most studied example and as a model for the behaviour of other members of its class. Significant advances in the understanding and development of electrochromic displays are highlighted. Fabrication and performance of display electrode and complete display cells based on these materials is described and compared, suggestion put forward regarding the most promising electrochromic material/electrolyte combinations for further study. Emphasis is placed on the method and details of film deposition or growth which determine film stoichiometry (including moisture content) and morphology and in turn strongly influence electrochromic behaviour.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call