Abstract
Reaction of compounds [(NO)2Fe(TMEDA)] and [BH4]- affords the first hydride-containing dinitrosyl iron complex (DNIC) [(NO)2Fe(η2-BH4)]- (2). Hydride-insertion reactivity of DNIC 2 promotes the reductive transformation of CS2 into DNIC [(NO)2Fe(η3-HCS2)]-, the first DNIC featuring both linear/bent NO ligands and Fe 3dz2-to-HCS2 π* backbonding interaction.
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