Abstract

Abstract Two perfluorinated palladium(II) pre-catalysts of the type (ArF 3P)2PdCl2 (ArF = m-C8F17-C2H4- C6H4 - and p-C7F15-CH2-O-C6H4-) could be highly activated with the co-catalyst B(C6F5)3/AlEt3 or methylalumoxane (MAO) for the vinyl/addition polymerization of norbornene. Their recycling was studied by using the FBS concept (Fluorous Biphasic System).

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