Abstract
C–X bonds in carbon tetrachloride, chloroform and 1-hexyl halogenides were transformed into C–H bonds in a transfer hydrodehalogenation reaction catalyzed by water soluble ruthenium(II) phosphine complexes. A turnover frequency of up to 1000 h −1 can be achieved when an aqueous solution of sodium formate is the hydrogen donor and RuCl 2(TPPMS) 2 ( 1) the catalyst (TPPMS= m-sulfophenyl diphenylphosphine sodium salt).
Published Version
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