Abstract
In the title compound, trans-[PdCl2{P(C7H7)3}2], where P(C7H7)3 is tri-m-tolylphosphine, the Pd atom is on an inversion centre, resulting in a trans-square-planar geometry. Selected geometric parameters are Pd—P and Pd—Cl distances of 2.3289 (4) and 2.2897 (4) Å, respectively, and a P—Pd—Cl angle of 87.77 (2)°. The effective cone angle for the tri-m-tolylphosphine is calculated to be 165°.
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