Abstract
In the title compound, (C20H26P)2[Pd2Cl6], the PdII atom within the hexachloridodipalladate(II) dianion has a square-planar geometry. It resides on a centre of inversion with the asymmetric unit containing half of the dianion and one phosphonium cation. Only weak C—H⋯π interactions are present in the crystal structure.
Highlights
In the title compound, (C20H26P)2[Pd2Cl6], the PdII atom within the hexachloridodipalladate(II) dianion has a squareplanar geometry. It resides on a centre of inversion with the asymmetric unit containing half of the dianion and one phosphonium cation
Weak C—H interactions are present in the crystal structure
We report that treatment of one such palladocycle, namely acetato-(2′-di-t-butylphosphino-1,1′-diphenyl-2yl) palladium(II), with HCl at room temperature results in the formation of the title compound (I) in good yield
Summary
Weak C—H interactions are present in the crystal structure
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