Abstract
The title compound, [Rh{P(OC7H7)3}2Cl(CO)], where P(OC7H7)3 is tris(2-methylphenyl)phosphite, crystallizes disordered over an inversion centre. Important geometrical parameters are Rh—P = 2.2905 (9) A, Rh—Cl = 2.402 (4) A, Rh—C = 1.764 (10) A, and C—Rh—Cl = 177.7 (5)°, P—Rh—Cl = 85.84 (12)° and Rh—C≡O = 174.7 (15)°. The effective cone angle for the phosphite ligand was calculated to be 167°.
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