Abstract

A thermodynamic analysis method with a new criterion was introduced to reveal and dynamic track the internal energy consumption distribution of natural gas combined cycle power plants with CO2 capture. The new method decomposes the capture energy consumption into separation energy consumption and system integration energy consumption caused by gas turbines, steam turbines, heat recovery steam generators and steam extraction. The results indicate that load variation has little effect on the energy penalty of the separation process, which accounts for over 50 % of the total capture energy consumption and is stable at around 0.8 MJe/kg CO2 for MEA-based cases, while the integration performance becomes better with load decreasing, since the superior matching between extraction steam and reboiler parameters. Besides, exhaust gas recirculation technology reduces energy consumption caused by steam extraction by around 67 %∼85 % and brings an additional penalty of 0.1–6 MW on the gas turbine under 40–100 % load conditions. Therefore, exploring new absorbents and optimizing the matching between extraction steam and reboiler parameters are the critical points for capture system without exhaust gas recirculation. In contrast, for capture system with exhaust gas recirculation, energy consumption caused by the deterioration performance of gas turbines is crucial under high operation load, while absorbent innovation is dominant at low load. With the aid of the thermodynamic analysis method introduced in this paper, a better understanding of CO2 capture systems under variable load conditions can be obtained, which may be helpful for reducing energy consumption in CO2 capture technologies.

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