Towards rational synthesis of inorganic solids

Abstract

There have been major advances in the past couple of years in the rational synthesis of inorganic solids: synthesis of mercury-based superconducting cuprates showing transition temperatures up to 150 K; ZrP 2−xV xO 7 solid solutions showing zero or negative thermal expansion; copper oxides possessing ladder structures such as La 1−xSr xCuO 2.5; synthesis of mesoporous oxide materials having adjustable pore size in the range 15–100 Å; and synthesis of a molecular ferromagnet showing a critical temperature of 18.6 K. Despite great advances in probing the structures of solids and measurement of their physical properties, the design and synthesis of inorganic solids possessing desired structures and properties remain a challenge today. With the availability of a variety of mild chemistry-based approaches, kinetic control of synthetic pathways is becoming increasingly possible, which, it is hoped, will eventually make rational design of inorganic solids a reality.