Towards a unified framework for anomalous transport in heterogeneous media

Abstract

Abstract We develop a unified framework to model the anomalous transport of tracers in highly heterogeneous media. While the framework is general, our working media in this study are geological formations. The basis of our approach takes into account the different levels of uncertainty, often associated with spatial scale, in characterizing these formations. The effects on the transport of smaller spatial scale heterogeneities are treated probabilistically with a model based on a continuous time random walk (CTRW), while the larger scale variations are included deterministically. The CTRW formulation derives from the ensemble average of a disordered system, in which the transport in each realization is described by a Master Equation. A generic example of such a system – a 3D discrete fracture network (DFN) – is treated in detail with the CTRW formalism. The key step in our approach is the derivation of a physically based ψ( s ,t) , the joint probability density for a displacement s with an event-time t. We relate the ψ( s ,t) to the velocity spectrum Φ(ξ) (|ξ|=1/v, ξ = v ) of the steady flow-field in a fluid-saturated DFN. Heterogeneous porous media are often characterized by a log-normal permeability distribution; the Φ(ξ) we use in this case is an analytic form approximating the velocity spectrum derived from this distribution. The common approximation of ψ( s ,t)∼p( s )t −1−β with a constant β, is evaluated in these cases. For the former case it is necessary to include s −t coupling while the latter case points to the presence of an effective t-dependent β. The full range of these features can be included in the CTRW solution but, as is shown, not in the fractional-time derivative equation (FDE) formulation of CTRW. Finally, the methods used for the unified framework are critically examined.