Toward the Creation of NMR Databases in Chiral Solvents for Assignments of Relative and Absolute Stereochemistry: Scope and Limitation

Nobuyuki Hayashi,Yoshihisa Kobayashi,Yoshito Kishi

doi:10.1021/ol010109r

Toward the Creation of NMR Databases in Chiral Solvents for Assignments of Relative and Absolute Stereochemistry: Scope and Limitation

Nobuyuki Hayashi, Yoshihisa Kobayashi + Show 1 more

https://doi.org/10.1021/ol010109r

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Journal: Organic Letters	Publication Date: Jun 20, 2001
Citations: 33	License type: cc-by-nc

Affiliation: Harvard University

#NMR Databases #Absolute Stereochemistry + Show 8 more

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Abstract

[structure: see text] Three additional NMR databases, 1-3, in a chiral solvent are presented. The C.21-C.38 portion of oasomycin A is used to demonstrate the scope and limitation of the universal NMR database approach in a chiral solvent for assignment of relative and absolute stereochemistry without degradation and/or derivatization.

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