Toward the creation of NMR databases in chiral solvents for assignments of relative and absolute stereochemistry: NMR desymmetrization of meso compounds.

Yoshihisa Kobayashi,Yoshito Kishi,Nobuyuki Hayashi

doi:10.1021/ol010110q

Toward the creation of NMR databases in chiral solvents for assignments of relative and absolute stereochemistry: NMR desymmetrization of meso compounds.

Yoshihisa Kobayashi, Yoshito Kishi + Show 1 more

https://doi.org/10.1021/ol010110q

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Journal: Organic letters	Publication Date: Jun 20, 2001
Citations: 29

Affiliation: Harvard University

#Absolute Stereochemistry #Assignments Of Stereochemistry + Show 7 more

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Abstract

[structure: see text] Examples of (13)C NMR desymmetrization of meso compounds are presented. On analysis of the NMR profiles of 1,3-diols, the additivity is recognized to predict the NMR profiles of 1,3,5-tirols.

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