Abstract
A couple of coppers: An efficient, asymmetric synthesis of the sedative cyclopeptide alkaloid paliurine F has been achieved. The strategy employs two copper(I)-mediated coupling reactions as key steps to install the aryl ether linkage as well as to form the enamide with a concomitant unprecedented macrocyclization. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2007/z602865_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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