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https://doi.org/10.1039/a802947d
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Cite Journal: Chemical Communications |  Publication Date: Jan 1, 1998 |
 Citations: 75 |
The sixteen-membered ring macrolide (–)-epothilone B 1 has been synthesized by a route which features stereospecific methylation of an (E)-γ,δ-epoxy acrylate, the use of a double asymmetric reaction employing (R,R)-diisopropyltartrate and (E)-crotylboronate, and ring closure by means of an olefin metathesis reaction.
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