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https://doi.org/10.1016/j.tet.2020.131661
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Cite Journal: Tetrahedron |  Publication Date: Oct 10, 2020 |
 Citations: 4 |
Affiliation: Indian Institute of Science Bangalore
Abstract Total synthesis of (+)-γ-lycorane is accomplished from (S)-ethyl lactate. Key disconnections in the synthesis involve an iterative Claisen and Overman rearrangement reactions to install the chiral centers in the tetrahydroindole moiety while, Pictet-Spengler reaction is used for the synthesis of the isoquinoline unit.
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