Abstract
Excess molar enthalpies, H ijk E , of 1,3-dioxolane or 1,4-dioxane ( i) + aniline ( j) + benzene or toluene ( k) ternary mixtures have been measured as a function of composition at 308.15 K. The H ijk E data have been fitted to Redlich–Kister equation to determine ternary adjustable parameters along with their standard deviations. It has been observed that H ijk E values predicted by Graph theory compare well with their corresponding experimental values. The observed data have been analyzed in terms of (i) Graph theory (which involves the topology of a molecule); (ii) Prigogine–Flory–Patterson; and (iii) Sanchez and Lacombe theories.
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