Tobacco Waste/Industrial Sludge Based Desulfurization Adsorbents: Effect of Phase Interactions during Pyrolysis on Surface Activity

Abstract

Industrial waste derived adsorbents were obtained by pyrolysis of tobacco waste with either metal sludge or waste oil sludge from a shipyard. The materials were used as media to remove hydrogen sulfide at room temperature in the presence of moisture. The initial and exhausted adsorbents after the breakthrough tests were characterized using sorption of nitrogen, thermal analysis, XRD, elemental analysis, and surface pH measurements. It was found that mixing tobacco and industrial sludges results in a strong synergy, enhancing the catalytic properties of adsorbents. This synergy is observed in both surface chemistry and porosity. During pyrolysis, new mineral phases are formed as a result of solid-state reactions between the components of the sludges. They are highly dispersed on the surface of mesopores. A high volume of these pores is a result of activation of the carbon phase in the composite by alkaline earth metals and also by the release of water from the decomposition of an inorganic phase that is in the predominant quantity. A high temperature of pyrolysis is beneficial for the adsorbents due to the enhanced activation of the carbonaceous phase and the chemical stabilization of the inorganic phase. Samples obtained at low temperatures are sensitive to water, which deactivates their catalytic centers.