Abstract
AbstractVinyl pivalate in the presence of the titanocene(II) reagent Cp2Ti[P(OEt)3]2 reacts both with nonpolar C≡C triple bonds and with polar C=O double bonds, to produce conjugated dienes and allylic alcohols, respectively. Similar alkenylation also takes place when (Z)‐alkenyl sulfones are treated with alkynes and carbonyl compounds. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)
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