Abstract

(TiCl3) [7705-07-9] Cl3Ti (MW 154.23) InChI = 1S/3ClH.Ti/h3*1H;/q;;;+3/p-3 InChIKey = YONPGGFAJWQGJC-UHFFFAOYSA-K (Zn) [7440-66-6] Zn (MW 65.39) InChI = 1S/Zn InChIKey = HCHKCACWOHOZIP-UHFFFAOYSA-N (reagent combination for the production of low-valent titanium which is used for the inter- and intramolecular reductive coupling of carbonyl and dicarbonyl compounds) Physical Data: see Titanium(III) Chloride and Zinc/Copper Couple. Solubility: unknown but presumably low in most organic solvents. THF and DME are the favored solvents for reactions involving this reagent combination. Handling, Storage, and Precautions: the low-valent titanium species produced by reacting TiCl3 with zinc/copper couple is generally made under an argon atmosphere immediately prior to use. The reagent may be pyrophoric and is certainly moisture sensitive.

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