Tin dioxide coated rice husk silica as lead-acid battery positive additive for enhancing the performance under power-intensive applications

Abstract

Lead-acid batteries rapidly response to instantaneous high-current, rendering them particularly effective for high-power applications, including power traction batteries, starter batteries, and start-stop systems. However, issues arise during intense working rate (6–10C), causing significant polarization that leads to severe oxygen evolution side reactions and softening and shedding of positive active material (PAM), limiting the battery's cycle life. This study introduces a tin dioxide (SnO2) coated rice husk silica (RH-SiO2) composite as an positive additive in lead-acid batteries. The composite (SnO2/RH-SiO2) has a hierarchical pore structure from RH-SiO2, provides a robust conductive framework. The lattice structure of the SnO2 is similar to that of PbO2, while induces the formation of a PbSnO3 intermediate phase during formation process. SnO2/RH-SiO2 can also accelerates lead dioxide deposition and improves the interphase conversion efficiency, while significantly enhances the transformation of α- and β-PbO2, leading to a 20.7% increase in discharge specific capacity. Compared to a standard battery, up to 3.7 times longer at 100% deep discharge cycle life and 4.7 times longer in start-stop-mode testing. In our finding the SnO2/RH-SiO2 composite serves as a highly effective additive for augmenting the performance and longevity of lead-acid batteries in high-power applications, presenting a significant advancement in battery technology.