Abstract

We describe dynamic dual quartz crystal microbalance measurements of redox driven ion and solvent transfers between poly(vinyl‐ferrocene) films and aqueous disodium naphthalene‐1,5‐disulfonate solutions. The relative transport rates are dianion > monoanion > solvent; salt does not participate. Solvent expulsion is faster than solvent entry. On short time scales during oxidation only dianion motion responds to electron transfer.

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