Time-dependent effective potential for the ultrafast correlated electron dynamics of molecules in intense laser fields: Application to anisotropic ionization of CO

Abstract

By using the multiconfiguration time-dependent (TD) Hartree-Fock (MCTDHF) method, we simulated the multielectron dynamics of a CO molecule irradiated by near-IR two-cycle pulses with different carrier envelope phases. The ionization rate calculated is higher when the laser electric field ε (t) points from the nucleus C to O than the opposite case, in agreement with the results of two-color ionization experiments. The mechanism of anisotropic tunnel ionization in CO was examined by converting the obtained multielectron dynamics to the representation in terms of TD natural orbitals {ϕj (t)}. Within the framework of MCTDHF, we derived the unitary equations of motion for {ϕj (t)}. From the derived equations, we defined the TD effective potentials that govern the dynamics of {ϕj (t)}. In for the 5σ HOMO, a narrow hump that originates from two-body electron-electron repulsion is formed on the top of the field-induced distorted barrier near the nucleus C when ε (t) points from C to O, which is responsible for the directional anisotropy of tunnel ionization. For 4σ HOMO-2, a high barrier to suppress ionization is formed in when ε (t) points from C to O, in correlation with the electron-electron interaction with a 5σ electron on route to ionization. For the opposite phase, becomes barrierless, which enhances high-harmonic generation through ϕ 4σ(t).