Tight ultrafiltration membrane: Preparation and characterization of thermally resistant carboxylated cardo poly (arylene ether ketone)s (PAEK-COOH) tight ultrafiltration membrane for dye removal

Abstract

Cardo poly (arylene ether ketone)s bearing hydrophilic carboxylic acid groups (PAEK-COOH) was successfully synthesized by condensation polymerization of 2-[bis(4-hydroxyphenyl)methyl] benzoic acid and 4,4′-bisfluorodiphenylketone. TGA and DSC analyses demonstrated that the material has an initial decomposition temperature and glass transition temperature of 360°C and 220°C respectively, which revealed the excellent thermal stability of PAEK-COOH. Then PAEK-COOH was employed to fabricate tight ultrafiltration membrane by the nonsolvent induced phase inversion process (NIPS). The water contact angle of the prepared membrane is 61.5°, indicating its good hydrophilicity. The PAEK-COOH tight ultrafiltration membrane possesses a pure water flux of 119.6±2.6Lm−2h−1, dye permeation flux of 100.9±4.3Lm−2h−1 and rejection of 99.8±0.33% for Congo red at dye concentration of 100ppm and operation pressure of 0.4MPa. Membrane has a molecular weight cut off of 9260Da and gives complete penetration of monovalent inorganic salt NaCl but a slight rejection of divalent inorganic salt Na2SO4 (less than 10%). Thus, the membrane could be used in the decolorization of wastewater or fractionation of dye and salt mixture for dye purification. The membrane also exhibits excellent antifouling performance and anti-dye adsorption properties with a flux recovery ratio of 91.5% for BSA and dye adsorption rate below 5.0% for four kinds of studied dyes, respectively.