Abstract

In this study, an in situ three-point bending test was carried out to study the mechanical properties and cracking behavior of the Cr-coated Zr-4 alloy considering the effect of pre-oxidation. The results showed that high temperature pre-oxidation led to the formation of intermetallic ZrCr2 at the coating/substrate interface and an α-Zr(O) layer beneath the interface. During the three-point bending test, the Cr coating and Zr-4 substrate showed good plastic deformation. However, the brittle intermetallic ZrCr2 diffusion layer exhibited cracks in the early stage, which accelerated the crack penetration to the Cr coating and the Zr-4 substrate, leading to the pre-failure of the pre-oxidized sample.

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