Three-Dimensionally Ordered Mesoporous (3DOm) Carbon Materials as Electrodes for Electrochemical Double-Layer Capacitors with Ionic Liquid Electrolytes

Abstract

Compared to rechargeable batteries, electrochemical double-layer capacitors (EDLCs) are normally considered to be higher power but lower electrical energy density charge storage devices. To increase the energy density, one can enlarge the interfacial area between electrodes and electrolyte through the introduction of nanopores and employ electrolytes that are stable over wider voltage ranges, such as ionic liquids. However, due to the relatively high viscosity of ionic liquids and large ion sizes, these measures can result in diminished power performance. Here, we describe the synthesis of carbon electrodes that overcome these limitations and simultaneously provide high specific energies and high specific powers in EDLCs using the ionic liquid EMI-TFSI as an electrolyte. A colloidal crystal templating method was optimized to synthesize three-dimensionally ordered mesoporous (3DOm) carbons with well-defined geometry, three-dimensionally interconnected pore structure and tunable pore size in the range from ...