Three-dimension TiO2@NiFe-layered double hydroxide core-shell heterostructures for enhanced photocatalytic phenol hydroxylation

Abstract

One-step selectively photocatalytic phenol hydroxylation to produce Dihydroxybenzenes (DHB) is an attractive and challenging strategy. However, the rapid recombination of photogenerated carriers existed in single component photocatalyst seriously hinders the photocatalytic efficiency. The heterojunction strategy can optimize the band structure of the photocatalyst, and effectively improve the carriers' separation and transfer during the photocatalytic process. Herein, we successfully designed and prepared a 3D TiO2@Ni3Fe1-LDH core-shell heterostructure photocatalyst by coupling TiO2 nanorods with Ni3Fe1-LDH nanosheets for the photocatalytic phenol hydroxylation to produce DHB. The results showed that the 3D TiO2@Ni3Fe1-LDH core-shell heterostructure had a suitable energy band structure for the photocatalytic phenol hydroxylation and the heterostructure accelerated the carriers’ separation and transfer. Meanwhile, the high porosity and abundant active sites were conducive to the adsorption of H2O2 and the photogenerated carriers transfer efficiency from the photocatalyst to H2O2. The 3D TiO2@Ni3Fe1-LDH core-shell heterostructure showed excellent photocatalytic performance of phenol hydroxylation, where the phenol conversion was 48.6%, and the selectivity of DHB was 81.1% at 25 °C and 4 h of light illumination. Furthermore, the as-prepared photocatalysts exhibited good stability after four cycles of experiment. This work provided a convenient and efficient method for the green synthesis of DHB.