Thorium removal by different adsorbents

Abstract

The removal of radiotoxic Th 4+ from aqueous solutions has been explored using two different groups of adsorptive materials (e.g. two activated carbons and four zeolites—two natural and two synthetic). The activated carbons were prepared from solvent extracted olive pulp (SEOP) and olive stone (OS) by a two-step physical activation method with steam. They were characterized by N 2 at 77 K adsorption, Hg porosimetry and by determination of their iodine number. All carbons prepared are of the H-type (e.g. contain mainly basic surface oxides) confirmed by the results of the Boehm’s method . The natural zeolites, clinoptilolite (NaCLI) and mordenite (NaMOR), were pretreated with Na + before the adsorption experiments, while the synthetic ones, NaX and NaA, were provided in their commercial sodium form. The natural zeolites, NaCLI and NaMOR, utilized 11.5 and 38.6% of the theoretical ion-exchange capacity, based on Al content, respectively, while NaX and NaA utilized 41.5 and 45.9%, respectively. The activated carbons showed better removal capability than NaCLI. NaMOR, showed comparable results to the carbon originated from OS, but lower removal capability than the carbon originated from SEOP. The synthetic zeolites showed the highest removal ability for thorium ions due to their increased ion-exchange capacity because of their cleaner and larger framework channels and their higher number of ion-exchange sites. The carbons adsorption capacity mainly depends on the content and nature of functional surface groups. The adsorption data were fitted to Langmuir and Freundlich models. The former achieved best fits and was further applied to obtain the respective Langmuir constant and maximum adsorption capacity for each system.