Abstract
Thorium(IV) thiocyanate, chloride and nitrate complexes with Schiff bases L ( ortho-XC 6H 4CH NC 6H 4COOH) derived from o-XC 6H 4CHO and 2-carboxyaniline have been prepared. The ligands acted as deprotonated uninegative tridentate molecules when X OH or deprotonated uninegative bidentate ones when X Cl, OCH 3 or NO 2. The resulting thorium(IV) centres in the complexes are therefore eight- or six-coordinated, respectively.
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