Abstract

Rectifying photosensitive structures of the ITO/P(Si)/CuPc type have been synthesized based on a heterojunction between a homoconjugated organosilicon polymer P(Si) and copper phthalocyanine CuPc. The maximum voltage responsivity of the samples (∼1 V/W at T = 300 K) was observed when the structure was illuminated from the P(Si) side. In this illumination mode, thin-film photovoltaic converters based on the proposed heterojunction exhibit a fine structure in the photosensitivity spectrum. It is suggested that the new structures can be used as selective photosensors.

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