Thermoluminescence study of X-ray irradiated muscovite mineral under various heating rate

Abstract

The thermoluminescence (TL) glow curves of X-ray irradiated micro-grain natural muscovite were recorded within 298–520K at various linear heating rates (2K/s, 4K/s, 6K/s, 8K/s and 10K/s). Natural TL of muscovite was checked, but no significant TL was observed within 298–520K in any heating rate. Within the heating rate 2–10K/s only a low temperature distinct peak was observed in the temperature range 348–357K. The TL parameters such as activation energy, order of kinetic, geometrical symmetry factor and pre-exponential frequency factor were investigated from the glow peak by Peak Shape (PS) method and Computerized Glow Curve Deconvolution (CGCD) technique. At lowest heating rate the glow peak obeys non-first order kinetic and at the highest heating rate it follows the second order kinetic. The variation of peak integrals, peak maximum temperatures, FWHM and activation energy with heating rates were investigated, and the glow curves at higher rates were found to be influenced by the presence of the thermal quenching. The thermal quenching activation energy and pre-exponential factor were calculated and found to be 2.31±0.02eV and 3.46×1014s−1, respectively.