Abstract
The solubility of eight calix[4]arenes and crown-calix[4]arenes in n-hexane at five different temperatures was determined by isothermal saturation. The thermodynamic dissolution parameters were calculated. Thermodynamics of solvation in n-hexane was calculated using thermodynamic parameters of sublimation obtained earlier. Thermogravimetric analysis of the bottom phase was carried out to detect crystallosolvates. The stoichiometry of the crystallosolvates formed was ascertained.
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