Abstract

The thermodynamic properties of solutions containing 2-methyl-1-propanol and acetonitrile have been analysed using an association model, which assumes the self-association and solvation of 2-methyl-1-propanol and acetonitrile, and includes a non-polar interaction term given by the NRTL equation. Vapour-liquid and liquid-liquid equilibria and excess molar enthalpy data for ternary mixtures including 2-methyl-1-propanol, acetonitrile and a non-associating component have been predicted by the association model using binary parameters only.

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