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Abstract
Vapour-liquid and liquid-liquid equilibria and excess molar enthalpy data for ternary mixtures formed by 2-methyl-2-propanol, acetonitrile and a non-associating component have been predicted using an association model with binary parameters obtained from constituent binary systems. The model assumes the association of the alcohol and acetonitrile and solvation between unlike molecules, allowing for a non-polar interaction term given by the NRTL equation.
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