Abstract
AS PART of a larger program of thermodynamic investigation of basicities of various organic amines, calorimetric measurements have been made on triethylenediamine to obtain A H values for ionization of the monoand diprotonated species of this substance in aqueous solution. Triethylenediamine is of particular interest because of its chemical and structural relations to such compounds as ethylenediamine and triethylamine, and also because of recent interest in this compound as a ligand in complexes of transition elements.
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