Abstract
Nagata I. and Sano M., 1992. Thermodynamics of associated solutions containing aniline and methanol. Fluid Phase Equilibria , 72: 147-162. Excess molar, enthalpies of aniline-methanol-benzene mixtures were measured with an isothermal dilution calorimeter at 25°C. Experimental results for three binary mixtures constituting the ternary mixture are well correlated by use of the UNIQUAC associated-solution model. The ternary experimental results are in close agreement with predicted values obtained from the model having binary parameters. The model is able to satisfactorily predict ternary liquid-liquid equilibria for aniline-methanol- n -hexane and aniline-methanol- n -heptane mixtures using binary information.
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