Thermodynamics of acetone—chloroform mixtures

Abstract

Apelblat, A., Tamir, A. and Wagner, M., 1980. Thermodynamics of acetone—chloroform mixtures. Fluid Phase Equilibria, 4: 229–255. The excess thermodynamic functions G E, H E, S E, C p E and V E and the vapour—liquid equilibria at constant temperature, at constant pressure and azeotropic behaviour are satisfactorily described for the acetone + chloroform system using the ideal association model of the type A + B + AB + AB 2. Existing data in the literature for the system were supplemented by determination of vapour pressures at 25.0° and 35.17°C, excess volumes of mixing at 35°C and excess heat capacities at 30°C.